MOLECULAR SPECTROSCOPY PART B
- Overview
- Assessment methods
- Learning objectives
- Contents
- Full programme
- Bibliography
- Teaching methods
- Contacts/Info
Quantum Mechanics is a standard prerequisite for this course. Part A of the course is a prerequisite for this course.
Oral examination on both part A and B of the course (30 min). Five questions:
2 questions on the content of section 1 as in the course program.
2 questions on the content of sections 2-7 as in the course program.
1 question on the spectra obtained in the lab.
The evaluation criteria will consider:
1) the completeness of the acquired knowledge.
2) ability to report critically about the advantages and limitations of the different techniques.
3) ability to indicate the more appropriate spectroscopy to be used in different scenarios.
4) the technical terminology used.
• Knowledge and understanding
o the regions of the electromagnetic spectrum
o the main spectroscopic techniques
o spectroscopic transition rules
• Skills aims.
o Bottom-up approach to chemical problems
o Extraction of the information from an experiment using a coherent physical model
o Selection of the most suitable technique(s) according to the desired outcome
o Critical analysis of experimental results
• Communicative aims
o This lesson aims at helping learners become better able to explain the logic process that brings to the selection of a spectroscopic techniques.
• Autonomous assessment
o Selection of the spectroscopic approach
o Discussion of results
6. Photoelectron spectroscopy. (8 h)
6.1. Ionization processes and Koopmans theorem.
6.2. UPS, XPS, Auger spectroscopies.
6.3. Synchrotron radiation. XAS and XES spectroscopies.
6.4. Mössbauer spectroscopy.
7. Magnetic spectroscopies: principles and applications (8 h).
7.1. Nuclear magnetic resonance (NMR).
7.2. Electron paramagnetic resonance (EPR).
8. Laboratory (24 h). Measurement of the IR spectra of simple organic molecules and sodium salts using different methods (transmission, KBr pellets, ATR).
6. Photoelectron spectroscopy. (8 h)
6.1. Ionization processes and Koopmans theorem.
6.2. UPS, XPS, Auger spectroscopies.
6.3. Synchrotron radiation. XAS and XES spectroscopies.
6.4. Mössbauer spectroscopy.
7. Magnetic spectroscopies: principles and applications (8 h).
7.1. Nuclear magnetic resonance (NMR).
7.2. Electron paramagnetic resonance (EPR).
8. Laboratory (24 h). Measurement of the IR spectra of simple organic molecules and sodium salts using different methods (transmission, KBr pellets, ATR).
Modern Spectroscopy, 4th edition - J. Michael Hollas; John Wiley & Sons.
Molecular Quantum Mechanics, Peter W. Atkins, Ronald S. Friedman, Oxford University Press.
Lecture notes will be provided for the sections on the synchrotron light and UV, XAS-XES spectroscopies.
Slides showing examples of spectra obtained with the different techniques will be also provided.
Frontal classes (16 h).
IR laboratory (24 h).
Contacts/Info: Every day by email appointment.